Hamilton’s Principle and Energy Profitability

Authors: Korotkevich S.V
DIN
IJOER-SEP-2025-3
Abstract

The kinetics of the interface between metals under contact and external influences (triboloading, rolling, physical and chemical effects of the environment, etc.) has been investigated. It is shown that the kinetics of the evolution of the structure of materials proceeds in accordance with the minimum production of entropy and maximum destruction. The conditions for obtaining a special nonequilibrium state of the crystal lattice of nickel under triboloading are determined. The main regularities of the kinetics of structural transformations, structural-scale levels of deformation and the properties of the interface between metals during contact and external interaction have been determined.

Keywords
principle of least action energy profitability nanocrystalline and submicrocrystalline structures invariants; dislocations stresses laws of kinetics entropy destruction.
Introduction

The accumulated experimental database in the field of research of metal interface kinetics does not allow to use it to the full extent to create a database, for example, on tribotechnical characteristics and wear. The experimental data given in different sources differ from each other. On the one hand, this can be explained by some differences in the modes and technologies of obtaining the surface, as well as the conditions of their testing, and on the other hand by the lack of scientifically sound fundamental principles and, as a consequence, measurement parameters. The fragmentation of fundamental research directions and purely practical approach to solve applied and immediate problems, unfortunately, does not allow to concentrate efforts on classification and systematization of data in the fields of metallophysics, tribochemistry, condensed state physics and nanomaterial science. The obtained results of plastic deformation studies are often controversial and sometimes contradictory. The current state of the problem of studying the surface kinetics of metals and the creation, including nanomaterials is characterized as a transitional period between the accumulation of experimental data and their interpretation in the categories of mechanics, physics, chemistry and the development of generalizing invariants and regularities that do not depend on the modes, conditions and technologies of their production [1, 2].

The lack of a systematic approach leads to the fact that the problem of contact interaction of surfaces of different materials in terms of optimal selection to improve their wear resistance has not yet been solved. Experimenters, unfortunately, do not take into account the large-scale factor of external influence, for example, load-velocity parameters on the surface of materials. Obtaining a momentary and quick “positive” result of research puts the experimenter in the limited conditions of hard, not soft impact on the material. As a result, as a rule, many processes (heat conduction, diffusion, mass transfer, hardening, amorphization, fracture, etc.) occur simultaneously and we cannot divide a complex process into composite and simpler ones. It is this systematic and thorough approach that allows researchers to divide a complex process into simple processes and establish the course of the dominant process in their diversity and, as a consequence, to identify and establish the main fundamental regularities describing this simple process. The level of understanding of the problem by the author of this article is fully consistent with the works and statements of R. Feyman, V.D. Kuznetsov and I.V. Kragelsky [3–5] and others. The most common fatigue [6], energy [7] and lobe [8] theories do not consider the kinetics of layer-by-layer hardening and fracture of the surface layer of metals in detail, taking into account all (nano, micro, meso and macro) structural and scale levels of deformation. The mechanisms of fragmentation and relaxation channels of strain energy accumulated in the surface layers of conjugated materials are not fully understood.

Conclusion

The physical essence of the processes: heat conduction, diffusion, mass transfer, hardening, amorphization, fracture, etc., occurring at contact localized interaction of metal surfaces, and the result is the same and does not depend on the way of its description. The work done or the response of a physical system (material) is commensurate with the magnitude of the external influence. It does not matter what mathematical approach we use (calculus of variations to describe IPA or differential equations based on Newton's laws, continuum physics, kinetics of physical and chemical processes) to describe physical processes in a solid body.

The main thing is the result in the form of minimum energy costs for the formation, evolution and destruction of a structure with certain properties. However, the PLA (Hamilton’s principle) is a more basic and fundamental principle, as it describes equilibrium and non-equilibrium processes than the minimum or maximum of entropy production for describing nonequilibrium processes. In addition, the use of PLA implies, based on the properties of space and time symmetry, the search and establishment of invariants, which does not follow from the principle of energetic favorability. The latter is most important as it has practical value in the study and evolution of the properties of emerging structures. Analysis of literature data and the existence of invariants, for example, in chemistry (D.I. Mendeleev's table, the law of conservation of mass during chemical reactions), biology (Mendel's second law), nuclear and quantum physics (conservation laws, etc.) determine the fundamentality and universality of the use of PLA and energy benefits for processes occurring in the space-time continuum. The issue of the inverse effect of material properties on the properties of the space-time continuum is debatable and open to further research.

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